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The Friedel-Crafts alkylation involves the electrophilic substitution of alkyl groups on aromatic rings when arenes are treated with alkyl halides in presence of Lewis acids. Aniline does not undergo alkylation since the newest casinos pair on nitrogen newest casinos amino group forms coordinate bond with AlCl 3preventing the complexation to alkyl halides.

This complex may act as the electrophilic reagent or it may dissociate to give a free carbocation, which can act as electrophile. However it is not as stable as the initial aromatic system. This is one of the drawback of this reaction. However, toluene is even more reactive than benzene and hence may undergo further substitution to give a mixture of polymethylated benzenes. The propyl carbocation is rearranged to more stable isopropyl carbocation by hydrogen ion shift during the reaction.

Hence the major product is cumene rather than propyl benzene. However if the reaction is carried out at room temperature, the major product is propyl benzene.

The carbocation is generated by using a protic acid. The proton is http://softwaresavvysub.info/cash-casino-red-deer.php to the the doubly bonded carbon so as to generate the more stable carbocation. Cumene can also be prepared by the when benzene is treated with propylene gas under 30 atm of pressure in presence of H 3 PO 4. Again the stable secondary carbocation is generated from the alkene during the reaction.

Sulfuric acid can also be used as catalyst. In this reaction, t-butyl carbocation is generated via dehydration of protonated alcohol. Hence a sequence of alkylation and dealkylation steps are possible through out the reaction.

This may sometimes lead to newest casinos products under thermodynamic control go here such as prolonged reaction times or newest casinos high temperatures.

Toluene undergoes ortho and para substitutions when treated with chloromethane at room Она online gambling new zealand подошла to give ortho and para xylenes. However newest casinos xylene is formed as the major product when the reaction newest casinos is heated to 80 o C. The meta substitutions occur due to less steric interactions. The initially formed mono substituted product directs the orientation newest casinos second ethyl group at ortho and para positions.

However these kinetically favored but thermodynamically less stable products may undergo dealkylation and prefer to take the meta position during the prolonged hours newest casinos the reaction.

The two chlorine atoms of dichloromehtane methylene chloride newest casinos replaced by benzene rings. Click the following article same product is obtained when benzene is treated with benzene under Friedel-Crafts conditions. The replacement of fourth halogen atom is not possible due to steric hindrance.

The pentamethyl and hexamethyl benzenes are also formed as side products.


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